One Piece Season 2 Episode 76
Time to Fight Back! Usopp’s Quick Thinking and Fire Star!
Usopp frees Luffy from Miss Goldenweek's control. With Karoo's help, Usopp and Luffy rescue the others, who take on Mr. 5 and Miss Valentine. Luffy and Karoo pursue Mr. 3 and Miss Goldenweek into the forest.